The electrocatalytic CO2 recycling into excessive added-value merchandise has been attracting large consideration for years. Co-feeding CO2/CO and utilizing tandem catalysts now are well-recognized methods to facilitate C–C coupling and the manufacturing of C2+ merchandise. In a pioneering paper printed in 2019 in Nature Nanotechnology, Wang et al. introduced preliminary evidences concerning the dominant contribution of the *CO (from CO)–*CO (from CO2) cross-coupling pathway over a large electrode potential vary and designed tandem catalysts that realized enhanced ethylene manufacturing charge (Nat. Nanotechnol. 14, 1063–1070; 2019).